The data set comprises trace metal and isotope data from the GEOTRACES programme. The data set incorporates the core GEOTRACES parameters for example, Iron (Fe), Aluminum (Al), Zinc (Zn), Manganese (Mn), Cadmium (Cd), Copper (Cu), delta 15 Nitrogen, delta 13 Carbon, Thorium (Th) isotopes, Protactinium(Pa) isotopes, Lead (Pb) isotopes, Neodymium (Nd) isotopes and aerosols, These data are also supported by ancillary measurements. GEOTRACES is global in scope and consists of ocean sections complemented by regional process studies. The ocean sections are designed to cross regions that provide the most information about sources, sinks and internal cycling of trace elements and isotopes (TEIs). The programme started in 2006, with the first International Polar Year - GEOTRACES cruise, and aims to study all major ocean basins over the next decade. Advances in clean sampling protocols and analytical techniques provide an unprecedented capability for measurement of a wide range of TEIs. All measurements collected for GEOTRACES will use ultra clean techniques as many of the countries involved have built specialist winches, wires and conductivity-temperature-depth (CTD) units specifically for this programme. SAFe standards (standards developed following the Sampling and Analysis of Fe (SAFe) cruise) and GEOTRACES inter-calibration protocols provide quality control.The GEOTRACES programme builds on the data collected during the Geochemical Ocean Section Study (GEOSECS) in the 1970s. The potential afforded by advances in sampling protocol and analytical techniques had not been realized since then, largely because of a lack of coordinated research. The GEOTRACES programme includes scientists from approximately 30 nations, although the key countries are the UK, Germany, France, Spain, Sweden, Netherlands, USA, Canada, New Zealand, Australia, Japan, India and China.

The data set comprises measurements of temperature, salinity, oxygen, chlorophyll and nutrients from two locations near Port Erin, Isle of Man. Sea surface temperature has been measured at Port Erin breakwater (54 05.113N, 04 46.083W) on a twice-daily basis from 1904 to the present day, accompanied by twice-daily sea surface salinity measurements since 1965. Since 1954, further measurements have been taken at the Cypris station in Port Erin Bay, 5km west of Port Erin (54 05.5N, 004 50.0W). The Cypris data have been collected at frequencies ranging from weekly to monthly depending on season, boat availability and weather, and comprise measurements of temperature at 0, 5, 10, 20 and 37m since 1954; salinity, dissolved oxygen and phosphate at 0 and 37m since 1954; silicate at 0 and 37m since 1958; nitrate and nitrite and 0 and 37 m since 1960; chlorophyll a at 0 m since 1966; ammonia at 0 and 37m since 1992; total dissolved nitrogen at 0 and 37m from 1996-2005; and total dissolved phosphorus at 0 and 37m from 1996-June 2002. At Port Erin temperatures were recorded using a Meteorological Office issue thermometer from the mid-1900s to October 2006. Since then Vemco temperature autologgers and Star-Oddi DST CTD loggers have been deployed from the Port Erin lifeboat slip and are exchanged on an approximately monthly basis. Until November 1961 temperature was recorded in degrees Fahrenheit; these data have since been converted to degrees Celsius. At the Cypris station water samples were collected with either a Nansen-Pettersen or an NIO bottle from 1954-2005. The Nansen-Pettersen bottle was used in conjunction with an insulated thermometer, while the NIO bottle was used in conjunction with a mercury reversing thermometer. From 2006 onwards an RTM 4002 X digital deep sea reversing thermometer has been used with an NIO bottle. Salinity was determined by titration against silver nitrate until 1965, thereafter using inductively coupled salinometers (Plessey 6230N until June 1998; Guildline Portasal from July 1998). Nutrients are estimated colorimetrically and dissolved oxygen is determined by the Winkler technique. Until 2006 chlorophyll-a was estimated using the trichromatic methods recommended by SCOR-UNESCO Working Group 17. Since that year the spectroscopic methods of Aminot & Rey (2000) have been used. Dissolved nitrogen and phosphorus were measured using the persulphate digestion method adapted from Valderama (1981). The Cypris station data are frequently split into the Cypris I (D. John Slinn) data set comprising data from 1954-1992 and the Cypris II data set from 1992-present. Data from the Port Erin and Cypris stations are sometimes known collectively as the ‘Port Erin Bay’ data set. Data from Port Erin Bay form part of the Isle of Man GAL Coastal Monitoring Sites network, which is described in a separate EDMED entry. The data were collected by the Port Erin Marine Laboratory (part of the University of Liverpool) until its closure in 2006. Sampling has since been taken over by the Isle of Man Government Laboratory. The data are managed by the British Oceanographic Data Centre.

The data set comprises measurements of temperature, salinity, oxygen, chlorophyll and nutrients from six locations near Port Erin, Isle of Man. The data collected at Port Erin breakwater (54 05.113N, 04 46.083W) and the Cypris station in Port Erin Bay (54 05.5N, 004 50.0W) are described separately in the "Port Erin (Isle of Man, Irish Sea) Temperature, Salinity and Nutrient Data Set (1904-)". The remaining four stations are described here. Data have been collected at the Resa (also known as Bayrnagh), approximately 5km east of Santon Head, Isle of Man (54 05.00N, 04 30.00W) at least once per month since 1994, with a hiatus from 2003-2006. The data comprise measurements of temperature at 0, 5, 10, 20 and 37m; salinity, dissolved oxygen, phosphate, nitrate, nitrite, silicate and ammonia at 0 and 37m; and chlorophyll-a at the surface. Total dissolved nitrogen was also measured at 0 and 37m between 1996 and 2003, while total dissolved phosphorus was measured at 0 and 37m between 1996 and June 2002. Corresponding data have been collected at Laxey Bay (54 12.00N, 04 23.00W), Ramsey Bay (54 20.47N, 04 17.47W) and Jurby Head Targets area (54 21.50N, 04 38.00W) at least once a month since 2006. Laxey Bay data comprise temperature at 0, 5, 10, 20 and 24m; salinity, dissolved oxygen, phosphate, nitrate, nitrite, silicate and ammonia at 0 and 24m; and chlorophyll-a at the surface. Ramsey Bay data comprise temperature at 0, 5, 10 and 19m; salinity, dissolved oxygen, phosphate, nitrate, nitrite, silicate and ammonia at 0 and 19m; and chlorophyll-a at the surface. Targets data comprise temperature at 0, 5, 10, 20 and 43m; salinity, dissolved oxygen, phosphate, nitrate, nitrite, silicate and ammonia at 0 and 24m; and chlorophyll-a at the surface. Prior to 2006 water samples and temperature measurements were collected using either a Nansen-Pettersen bottle with an insulated thermometer or an NIO bottle with a mercury reversing thermometer. Since 2006 an NIO bottle and a Sensoren Instrumente Systeme (SIS) RTM 4002 X digital deep sea reversing thermometer have been used. Salinity was determined by titration against silver nitrate until 1965, thereafter using inductively coupled salinometers (Plessey 6230N until June 1998; Guildline Portasal from July 1998). Nutrients are estimated colorimetrically and dissolved oxygen is determined by the Winkler technique, as outlined in Jacobsen et al. (1950). Until 2006, chlorophyll-a was estimated using the trichromatic methods recommended by SCOR-UNESCO Working Group 17. Since that year the spectroscopic methods of Aminot & Rey (2000) have been used. Dissolved nitrogen and dissolved phosphorus were measured using the persulphate digestion method adapted from Valderama (1981). The data were collected by the Port Erin Marine Laboratory (part of the University of Liverpool) until its closure in 2006. Sampling has since been taken over by the Isle of Man Government Laboratory (GAL). The data are managed by the British Oceanographic Data Centre.

The Shelf Sea Biogeochemistry (SSB) data set comprises hydrographic data, including measurements of temperature, salinity and currents, complemented by bathymetric and meteorological data. The study area is located in the Celtic Sea, shelf seas and shelf-edges around the United Kingdom and Republic of Ireland. The data were collected by a combination of research cruises that spanned from March 2014 to September 2015. Shipboard data collection involved the deployment of conductivity-temperature-depth (CTD) packages in the study area. Continuous measurements of current velocities (using vessel mounted ADCPs, VMADCPs), bathymetry and surface ocean and meteorological properties were collected throughout each cruise. Moorings were deployed in the Celtic Sea in early 2014 and provided approximately two years worth of hydrographic time series data. The SSB programme aims to increase the understanding of the cycling of nutrients and carbon and the controls on primary and secondary production, and their role in wider biogeochemical cycles, which in turn will significantly improve predictive marine biogeochemical and ecosystem models over a range of scales. SSB brings together UK researchers from Bangor University, Centre for Environment, Fisheries and Aquaculture Science (CEFAS), Meteorological Office, National Oceanography Centre (NOC), Plymouth Marine Laboratory (PML), Scottish Association for Marine Science (SAMS), University of Aberdeen, University of East Anglia (UEA), University of Edinburgh, University of Liverpool, University of Oxford, University of Portsmouth and University of Southampton. It also has UK and Irish partners, as Agri-Food and Biosciences Institute (AFBI), Marine Institute and Marine Scotland Science. The programme was divided into five work packages, having Jonathan Sharples as the Principal Investigator for work package 1 (CANDYFLOSS), Martin Solan as Principal Investigator for work package 2 (Biogeochemistry, macronutrient and carbon cycling in the benthic layer), Peter J. Statham as Principal Investigator for work package 3 (Supply of iron from shelf sediments to the ocean), Icarus Allen as Principal Investigator for work package 4 (Integrative Modelling for Shelf Seas Biogeochemistry) and Keith Weston as Principal Investigator for work package 5 (Blue Carbon – How much carbon is stored in UK shelf seas, what influences storage and could it be used in carbon trading?). All data will be managed by the British Oceanographic Data Centre (BODC).

The dataset comprises physical, biogeochemical and biological measurements of water column properties. Hydrographic profiles of water temperature, salinity, fluorescence, turbidity, attenuance, dissolved oxygen and photosynthetically active radiation were collected, and were supplemented by measurements of surface ocean (temperature, salinity, fluorescence, attenuance) and meteorological (air pressure, air temperature, humidity, wind, irradiance) properties, as well as bathymetry. A comprehensive water sampling program provided biogeochemical data including measurements of dimethyl sulphide (DMS), dimethylsulphionopropionate (DMSP), nutrients, halocarbons, methylamines, pigments, radiogeochemistry and dissolved organic carbon (DOC). Biological data were also collected, including samples of viruses, bacteria, phytoplankton, micro- and mesozooplankton. Currents throughout the water column were measured both at fixed locations and across the study area, while Lagrangian experiments provided further current data. The datqa were collected in the northern North Sea between 5th June 1999 and 1st July 1999 during RRS Discovery cruise D241. Hydrographic profiles were collected using a conductivity-temperature-depth (CTD) package with attached auxiliary sensors, an undulating oceanographic recorder (UOR), a vessel-mounted acoustic Doppler current profiler (ADCP), moored ADCP and temperature sensors, and a suite of standard underway hydrographic and meteorological sensors. Water samples for biogeochemical and biological analyses were collected from both the underway system and CTD bottles, while nets were deployed to collect zooplankton samples. Plankton samples were supplemented by respiration experiments conducted during the cruise. The Lagrangian current data were gathered from four drifters and a tracer experiment where the distribution of sulphur hexafluoride (SF6) released from the ship was monitored via water samples collected from the CTD and the underway system. A survey of the region was carried out in order to locate an Emiliania huxleyi bloom suitable for the study and the chosen bloom was labelled with the SF6 tracer. The biogeochemical process study followed the patch as it drifted in a SE direction and was eventually subducted under Norweigian coastal water on 26 June. The study aimed to investigate DMS biogeochemistry within a coccolithophore bloom. The research was organised by NERC's Plymouth Marine Laboratory and involved the University of East Anglia, Scottish Association for Marine Science, Dunstaffnage Marine Laboratory, Marine Biological Association, Defence Research Agency, and Southampton Oceanography Centre. Data management support for the project is provided by the British Oceanographic Data Centre (BODC). The dataset is available on CD-ROM and can be requested from BODC.

The UK Surface Ocean-Lower Atmosphere Study (UK SOLAS) marine fieldwork data set comprises all data, marine or otherwise, collected during sea-going activities. The fieldwork included eight dedicated research cruises in the eastern North Atlantic Ocean, spanning the period 2006-2008. These cross-disciplinary missions resulted in a diverse data catalogue. This includes meteorology (3-D wind speed and direction, total irradiance, Photosynthetically Active Radiation/PAR, air temperature, atmospheric pressure, humidity, aerosol optical thickness); atmospheric composition (carbon dioxide concentration, aerosol particle counts and size spectra, chemical analyses of aerosol particle composition, cloud condensation nuclei/CCN, concentrations of pollutants such as black carbon, concentrations of free radical species such as iodine monoxide and nitrate radicals); chemical and energy-fluxes across the air-sea boundary (dust deposition rates, oxygen and nitrogen fluxes, carbon dioxide fluxes, sensible heat fluxes, latent heat fluxes, momentum fluxes); biological, chemical and physical properties and processes in the sea surface micro-layer (chlorophyll concentration, bacterial production, phytoplankton and bacterial speciation, concentrations of biogenic trace compounds such as halocarbons, nitrous oxide, dimethyl sulphide/DMS and alcohols, surfactant concentrations, halogen concentrations such as iodine, iodide and iodate); biological, chemical and photochemical properties and processes in the ocean subsurface (primary productivity, trace gas production, plankton community composition, nutrient concentration, concentrations of trace metals such as iron, aluminium, manganese, magnesium and cobalt, ligand and complex metal chemistry parameters such as heme, dust dissolution, salinity, temperature, amino acids and urea, carbonate system chemistry including alkalinity); and sea-state physics (breaking waves, wave slope, whitecaps, bubble size spectra, aerosol formation, subsurface acoustics). Additionally, time series of air-sea fluxes were measured from the Norwegian weather ship, Polarfront, between 2006 and 2009. UK SOLAS scientists also participated in the Bergen Mesocosm experiment during 2008. This simulated gas exchanges and biological, chemical and photochemical properties and processes in the sea surface micro-layer under controlled conditions. The study united atmospheric and marine scientists from institutions across the UK and international collaborators. The UK SOLAS data set was intended to advance understanding of the mutual interactions between the atmosphere and the oceans, especially the chemical exchanges that affect ocean productivity, atmospheric composition and climate. It was funded by the UK Natural Environment Research Council, as the UK's contribution to the international Surface Ocean-Lower Atmosphere Study (SOLAS). The data are held at the British Oceanographic Data Centre (BODC) and have been incorporated into the National Oceanographic Database (NODB). Data collected from non-ship based activities, for example land-based atmospheric data and data resulting from campaigns using the Facility for Airborne Atmospheric Measurements (FAAM) aircraft are held at the British Atmospheric Data Centre (BADC).